Chemistry | KOH and NaOH | Inline potassium hydroxide (KOH) and sodium hydroxide (NaOH) measurement in the alkaline water electrolysis process for the production of green hydrogen

The alkaline water electrolysis becomes an important future key technology in the context of cli-mate change and decarbonization. For the efficient production of green hydrogen, an effective and reliable inline KOH or NaOH concentration measurement is of importance. Anton Paar’s unique sound velocity sensor L- Sonic 5100 Version MON is ideally suited for a 24/7 inline monitoring of the potassium hydroxide or sodium hydroxide concentration.

Alkaline water electrolysis for Power-to-X

The production of green hydrogen via alkaline water electrolysis will become a near future key parameter, especially for Power-to-X technology. Through the synthetic production of hydrogen via green electricity, other energy sources can be obtained or if possible di-rectly converted into energy. Currently, hydrogen is produced by means of natural gas reforming, but new inventions as well as the revival of the well-known technology of alkaline water electrolysis enable the production of green hydrogen. To do so, the chemi-cals KOH and NaOH as liquid alkaline electrolyte so-lution play a major role. The structure of an electrochemical cell consists of two conductive materials, so called electrodes, which are immersed in an ionically conductive liquid electro-lyte and electrically connected to each other. The sep-aration of water occurs in two partial reactions in the electrolysis cell. As soon as voltage is applied, hydro-gen is produced at the cathode and oxygen at the an-ode.
Potassium hydroxide (KOH) or sodium hydroxide (NaOH) is added as an electrolyte to increase the conductivity of the water.
For an efficient and reliable 24/7 monitoring of the electrolyte concentration, Anton Paar offers an easy-to-integrate and cost-efficient technology package consisting of the inline sound velocity sensor L- Sonic 5100 Version MON together with the power-ful evaluation unit Pico 3000.

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